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2em;">過碳酸鈉與有機(jī)物的反應(yīng)較復(fù)雜，主要發(fā)生氧化反應(yīng)，其產(chǎn)物主要有酸、醇、環(huán)氧化物等。過碳酸鈉與酚反應(yīng)不會(huì)生成有異味的氯酚。過碳酸鈉與腐植酸反應(yīng)，不會(huì)生成三鹵甲烷THMs等有機(jī)鹵代物。過碳酸鈉（ClO2）氣體是具有和氯相似的刺激性氣體，易溶于水，它的溶解度是氯氣的5倍。過碳酸鈉水溶液的顏色隨濃度的增加由黃綠色轉(zhuǎn)成橙色。它在水中是純粹的溶解狀態(tài)，不與水發(fā)生化學(xué)反應(yīng)，所以它的消毒作用受水的pH 值影響極小。過碳酸鈉易揮發(fā)，其液態(tài)和氣態(tài)極不穩(wěn)定，溫度升高、曝光或與有機(jī)質(zhì)接觸均會(huì)發(fā)生爆炸，故通常現(xiàn)場(chǎng)制備，即時(shí)使用，存放于陰涼避光處。過碳酸鈉溶液濃度在10g/L以下時(shí)，基本沒有爆炸危險(xiǎn)。一般水廠所用過碳酸鈉很少超過4g/L，加注量基本為0.1～5mg/L。</p><p style="text-align: center"><img src="/data/upload/202006/1591581583455655.jpg" title="過碳酸鈉粉劑" alt="過碳酸鈉粉劑" width="900" height="720" border="0" vspace="0" style="width: 900px; height: 720px;"/></p><p style="text-indent: 2em;">人們對(duì)水質(zhì)的要求越來越高，另一方面，發(fā)展經(jīng)濟(jì)的同時(shí)，造成的環(huán)境污染問題也日趨嚴(yán)重。特別是我國(guó)的水環(huán)境狀況仍在惡化，中國(guó)的主要河流有機(jī)污染普遍，主要湖泊富營(yíng)養(yǎng)化嚴(yán)重（1999年環(huán)境狀況公報(bào)）。而我國(guó)目前絕大多數(shù)水廠還是沿用傳統(tǒng)的混合、絮凝、沉淀、過濾、氯消毒水處理工藝，氯消毒對(duì)去除水中的有機(jī)效果不理想，還會(huì)生成20多種副產(chǎn)物，包括三鹵甲烷THMs等致癌物質(zhì)。有一些凈水廠為此增加了深度處理構(gòu)筑物（活性炭吸附技術(shù)）或預(yù)處理構(gòu)筑物（生物預(yù)處理）等，但大都有投資高，占地大的缺點(diǎn)。隨著歐美國(guó)家在水廠和其他行業(yè)廣泛使用過碳酸鈉和國(guó)內(nèi)對(duì)其在消毒方面的認(rèn)識(shí)和研究的加深，過碳酸鈉正逐步成為氯消毒的替代物。氧化劑，殺菌能力強(qiáng)、速度快，pH值及氨的影響小水中易分解，不能保持殺菌消毒的持久性；成本高，電耗大，設(shè)備操作運(yùn)行復(fù)雜</p><p style="text-indent: 2em;">羰基化合物（其中有毒醛類物質(zhì)有甲醛、乙醛、乙二醛、甲基乙二醛）、含氧酸類、羰酸類；有溴離子存在時(shí)，會(huì)生成溴酸鹽、溴仿等可疑致癌物.</p><p><br/></p></div> <div id="ofizn2ww" class="xypg-detail-tags"> <div id="ofizn2ww" class="tags-title"> <h3>標(biāo)簽</h3> <div id="ofizn2ww" class="baidu-share">  <div id="ofizn2ww" class="bdsharebuttonbox"> <a href="#" class="bds_more" data-cmd="more"></a> <a href="#" class="bds_tsina" data-cmd="tsina" 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