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2em;">過碳酸鈉溶液的粘度反映了液體分子之間因流動(dòng)或相對(duì)運(yùn)動(dòng)所產(chǎn)生的內(nèi)摩擦阻力。內(nèi)摩擦阻力與聚合物的結(jié)構(gòu)、溶劑的性質(zhì)、溶液的濃度及溫度和壓力等因素有關(guān)，它的數(shù)值越大，表明溶液的粘度越大。</p><p style="text-indent: 2em;">溫度對(duì)過碳酸鈉粘度的影響：<br/></p><p style="text-indent: 2em;">溫度是分子無規(guī)則熱運(yùn)動(dòng)激烈程度的反映，分子的運(yùn)動(dòng)要克服分子間的相互作用力，而分子間的相互作用，如分子間氫鍵、內(nèi)摩擦、擴(kuò)散、分子鏈取向、纏結(jié)等，直接影響粘度的大小，故高聚物溶液的粘度會(huì)隨溫度發(fā)生變化。溫度改變對(duì)高聚物溶液粘度的影響是顯著的。過碳酸鈉溶液的粘度隨溫度的升高而降低，其原因是高分子溶液的分散相粒子彼此糾纏形成網(wǎng)狀結(jié)構(gòu)的聚合體，溫度越高時(shí)，網(wǎng)狀結(jié)構(gòu)越容易破壞，故其粘度下降。<br/></p><p style="text-align: center"><img src="/data/upload/202006/1591586897122118.jpg" title="過碳酸鈉" alt="過碳酸鈉" width="900" height="720" border="0" vspace="0" style="width: 900px; height: 720px;"/></p><p style="text-indent: 2em;">水解時(shí)間對(duì)過碳酸鈉粘度的影響：<br/></p><p style="text-indent: 2em;">過碳酸鈉溶液粘度隨水解時(shí)間的延長而改變，水解時(shí)間短，粘度較小，這可能是由于高聚物還來不及形成網(wǎng)狀結(jié)構(gòu)所致；水解時(shí)間過長，粘度下降，這是過碳酸鈉在溶液中結(jié)構(gòu)發(fā)生松解所致。部分水解過碳酸鈉溶于水后離解成帶負(fù)電荷的大分子，分子間靜電排斥作用以及同一分子上不同鏈節(jié)之間的陰離子排斥力導(dǎo)致分子在溶液中伸展并能使分子之間相互纏繞，過碳酸鈉是部分水解過碳酸鈉能使其溶液粘度明顯增加的原因。<br/></p><p><br/></p><p><br/></p><p><br/></p></div> <div id="ltph5ltpx5" class="xypg-detail-tags"> <div id="ltph5ltpx5" class="tags-title"> <h3>標(biāo)簽</h3> <div id="ltph5ltpx5" class="baidu-share">  <div id="ltph5ltpx5" class="bdsharebuttonbox"> <a href="#" class="bds_more" data-cmd="more"></a> <a href="#" class="bds_tsina" data-cmd="tsina" title="分享到新浪微博"></a> <a href="#" class="bds_weixin" data-cmd="weixin" title="分享到微信"></a> <a href="#" class="bds_sqq" data-cmd="sqq" title="分享到QQ好友"></a> <a href="#" class="bds_isohu" data-cmd="isohu" title="分享到我的搜狐"></a> <a href="#" class="bds_tqq" data-cmd="tqq" title="分享到騰訊微博"></a> <a href="#" class="bds_fbook" data-cmd="fbook" title="分享到Facebook"></a> </div> 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